Standard Level Content
Unit 12  ·  IB Chemistry

Equilibrium

Analysis of reversible reactions that reach a state of balance, governed by the equilibrium constant and Le Chatelier’s principle.

SL HL ~ hrs
1 H 1.008
6 C 12.011
29 Cu 63.546
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Video Instruction

6 Lessons Available

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3 Equilibrium Exam Version A edited
3 Equilibrium Test Version B Edited
Equilibrium Graphs_Factors that affect Equilibrium
ICE Tables
Relationship between Gibbs free energy and Equilibrium Constant
The Equilibrium Constant and Reaction Quotient
12 Mg 24.305
10 Ne 20.180
equilibrium constant
the ratio of product concentrations to reactant concentrations at equilibrium, with each concentration raised to a power equal to the number of moles of that substance in the balanced chemical equation. Commonly denoted by Kc, Kp, or Ksp
reaction quotient
Ratio of the concentrations of the products to the concentrations of the reactants at any point during the reaction aside from equilibrium, where each reactant and product in the expression is raised to the power of its stoichiometric coefficient. Commonly denoted by Q.
Q = Kc
reaction is at equilibrium
Q>Kc
reaction proceeds left in favor of reactants
Q<Kc
reaction proceeds right in favor of products
heterogeneous equilibrium
a state of equilibrium that occurs when the reactants and products of a reaction are present in more than one physical state
homogeneous equilibrium
all the reactants and products are in the same physical state
Haber process
an industrial process for producing ammonia from nitrogen and hydrogen by combining them under high pressure in the present of an iron catalyst
contact process
industrial method of preparing sulfuric acid by the catalytic oxidation of sulfur dioxide
methanol production
Ì CO (g) + 2H2(g) CH3OH (g Used as starting materials for other chemicals + fuels Lower temp (227C)= favours exo reaction therefore higher yield Higher pressure (10000KPa)= favours forwards reaction as this decreases number of gaseous molecules BUT too high = too expensive catalyst= chromium
dynamic equilibrium
condition of continuous, random movement of particles but no overall change in concentration of materials
Le Chatelier's Principle
when stress is applied to a system at equilibrium, the system changes to relieve the stress
concentration
factor that affects equilibrium by the reaction shifting in the direction to restore the change in concentration of reactant/product
exothermic reaction
for a system at equilibrium, increasing temperature will shift the reaction to the left.
endothermic reaction
for a system at equilibrium, increasing temperature will shift the reaction to the right.
closed system
A system in which no matter is allowed to enter or leave
pressure
for a gaseous system at equilibrium, an increase in pressure will cause the system will shift to the side with less moles of gas.
catalyst
increases the rates of both the forward and the reverse reactions equally
26 Fe 55.845
79 Au 196.967
17 Cl 35.45